Grill or broil the poblanos until blackened. Place in a sealed container to sweat until cool, then peel and remove seeds, taking care to keep the chiles as whole as possible. Place in a heat-proof container for storing the finished pickles.
Heat the oil in a large, deep skillet over medium heat. Add onions and cook, stirring occasionally, until soft and beginning to brown.
Add garlic and cook, stirring, until soft and very fragrant.
Add oregano, thyme, bay, cloves, and peppercorns. Cook briefly, stirring to incorporate.
Add in vinegars, salt, and sugar, stirring to combine. Simmer briefly, stirring to dissolve sugar.
Pour the brine over the chiles. Let cool to room temperature, then cover and refrigerate.
Let marinate for at least a few hours before use.